INST Faculty Directory
Dr Kamalakannan Kailasam
Scientist E
Educational Qualification:

♦ Ph.D. (2008): Department of Chemistry, University of Stuttgart, Stuttgart, Germany
♦ M.Sc. (2002): Department of Chemistry, Bishop Heber College, Bharathidasan University, Tiruchirappalli, Tamil Nadu

Research Career :

♦ Associate Professor (Scientist-E); Institute of Nano Science & Technology, Mohali, India; April 2015 onwards
♦ Postdoctoral Research Fellow, Technical University of Berlin, Berlin, Germany (February 2010 – April 2015)
♦ Postdoctoral Research Fellow, Max Planck Institute of Colloids and Interfaces, Potsdam-Golm, Germany (February 2009 – January 2010)

Research interests :

Advanced Functional Nanomaterials for Energy and Environmental Applications like water splitting, CO2 conversion, gas storage, fine chemicals production, photovoltaics, fuel cells and batteries. 
My approach mostly depends on creating porosity in functional organic and inorganic materials by soft and hard templating approaches and their extensive characterization. In addition building the organic porous network by reacting special tectons and avoiding their packing in such a way that it opens up the porosity, for eg., in Covalent Organic Frameworks (COFs). As the further step, to fulfil like every scientists dream, of extending the research results to develop technology by prototype devices and towards industrial applications:
Conversion of water resources to fuels by solar energy: Porous heptazine and triazine based polymeric carbon nitride and mesoporous WO3 and BiVO4 semiconductors for photocatalytic and photoelectrochemical visible light water splitting and organic conversions.
Storage of H2, CO2 and CH4; capturing and conversion of green house gases (GHGs) like CO2: Covalent Organic Frameworks (CTFs, Covalent Triazine Frameworks), Mesoporous melamine resins and Polymeric carbon nitrides
Conversion of Biomass and CH4 to value-added fuels: Porous mixed metal oxide and metal nanoparticle supported SBA-15, MCM-41 and mesoporous zeolites. Hydrothermal Carbonization (HTC) of the biomass into functionalised carbon materials.
Electrochemical applications: Porous hetero atom doped carbons from renewables, graphene/CNT carbon nitride composites, CTFs, mesoporous metal oxides for Fuel cells, Batteries and Supercapacitors
Chromatographic applications: Various morphological forms, like M-MCM-41 (e.g., M = Ti) silica spheres grafted with functional chains for on-column catalysis and separation using HPLC/GC techniques
Environmental Remediation-water purification: Carbon nitride polymers – removal of toxic/heavy elements from polluted water, photocatalytic adsorption/degradation of dyes and other organic pollutants from industrial wastes

Biotechnology applications: Porous carbon nitrides as Fluorescence nanoprobe in biosensing and bioimaging applications. Multi-functionalized ordered porous spherical silicas as drug-delivery systems.

Awards & Recognitions:

♦ Max Planck Fellowship for Postdoctoral Research, Max Planck Institute for Colloids and Interfaces-Potsdam, Germany – 2009
♦ DFG (German Research Council) Doctoral Fellowship, University of Stuttgart, 2004
♦ IGCAR-DAE Junior Research Fellow (JRF), IGCAR-Kalpakkam, Tamil Nadu - 2004
♦ Best Outgoing Post-Graduate Student in Chemistry, Bishop Heber College, Bharathidasan University, Tiruchirappalli, Tamil Nadu – 2002
♦ Reviewer for Royal Society of Chemistry (RSC) and Elsevier journals

Publications:
    1.Deep-Blue OLED Fabrication from Heptazine Columnar Liquid Crystal Based AIE-Active Sky Blue Emitter“ I. Bala, L. Ming, R. A. K. Yadav, J. De, D. K. Dubey, S. Kumar, H. Singh, J. –H. Jou, K. Kailasam* and S. K. Pal. ChemistrySelect, 2018, 3, 7771–7777.
    2.Hydrogen-bond mediated columnar liquid crystalline assemblies of C3-symmetric heptazine derivatives at ambient temperature“ I. Bala, S. P. Gupta, S. Kumar, H. Singh, J. De, N. Sharma, K. Kailasam* and S. K. Pal*. Soft Matter, 2018, DOI: 10.1039/c8sm00834e.
    3.Natural sunlight driven oxidative homocoupling of amines by truxene based conjugated microporous polymer“ V. R. Battula, H. Singh, S. Kumar, I. Bala, S. K. Pal*,K. Kailasam*. ACS Catalysis, 2018, 8, 6751-6759.
    4.Hydrogen-bond mediated columnar liquid crystalline assemblies of C3-symmetric heptazine derivatives at ambient temperature“ Bhumica Agarwal, K. Kailasam* R. S. Sangwan and S. Elumalai. Renewable and Sustainable Energy Reviews, 2018, 82, 2408–2425.
    5.A Low Temperature, Highly Sensitive and Fast Response Toluene Gas Sensor Based on In(III)-SnO2 Loaded Cubic Mesoporous Graphitic Carbon Nitride“ R. Malik, V. K. Tomer*, V. Chaudhary, M. S. Dahiya, S. P. Nehra, S. Duhan and K. Kailasam*. Sens. Actuators B, 2018, 255, 3564-3575.
    6.A Low Temperature, Highly Sensitive and Fast Response Toluene Gas Sensor Based on   In(III)-SnO2 Loaded Cubic Mesoporous Graphitic Carbon Nitride“ R. Malik, V. K. Tomer*, V. Chaudhary, M. S. Dahiya, S. P. Nehra, S. Duhan and K. Kailasam*. Sens. Actuators B: Chem., 2017, doi: 10.1016/j.snb.2017.09.193.
    7.Truxene based Porous, Crystalline Covalent Organic Frameworks and it’s Applications in Humidity SensingH. Singh, V. K. Tomer, N. Jena, I. Bala, N. Sharma, D. Nepak, A. De Sarkar,* K. Kailasam* and S. K. Pal*. J. Mater. Chem. A, 2017, doi: 10.1039/C7TA05043G.
    8.“Heptazine: A new electron deficient fluorescent core for discotic liquid crystals” I. Bala, H. Singh, V. R. Battula, S. P. Gupta, J. De, S. Kumar, K. Kailasam* and S. K. Pal*. Chem. Eur. J., 2017, doi: 10.1002/chem.201703364.
    9.“Traversing the History of Solid Catalysts for Heterogeneous Synthesis of 5-Hydroxymethylfurfural from Carbohydrate Sugars: A Review” Bhumica Agarwalᶲ, K. Kailasam*, R. S. Sangwan and S. Elumalai. Renewable and Sustainable Energy Reviews,2017,doi.org/10.1016/j.rser.2017.08.088.
    10.“Near Room Temperature Ethanol detection using Ag-loaded Mesoporous Carbon Nitrides” V. K. Tomer, R. Malik and K. Kailasam*. ACS Omega, 2017, 2 (7), 3658–3668.
    11.“Excellent Humidity Sensor based on In-SnO2 Loaded Mesoporous Graphitic Carbon NitrideR. Malik, V. K. Tomer*, V. Chaudhary, M. S. Dahiya, S. P. Nehra, S. Duhan and K. Kailasam*. J. Mater. Chem. A, 2017, 5, 14134-14143.
    12.“Cubic mesoporous Ag@CN: A high performance humidity sensorr” V. K. Tomer, S.T. Nishanthi, S. Gahlot and K. Kailasam*. Nanoscale, 2016, 8, 19794-19803.
    13.“Silica material variation for MnxOy-Na2WO4/SiO2” M. Yildiz, Y. Aksu, U. Simon, T. Otremba, K.Kailasam, C. Göbel, F. Girgsdies, O. Görke, F. Rosowski, A. Thomas, R. Schomäcker and S. Arndt. Appl. Catal. A, 2016, 525, 168-179.
    14.Donor-Acceptor Type Heptazine-Based Polymer Networks for Photocatalytic Hydrogen Evolution” K. Kailasam*, M. B. Mesch, L. Möhlmann, M. Baar, S. Blechert, M. Schwarze, M. Schröder, R. Schomäcker, J. Senker and A. Thomas*. Energy Technology, 2016, 4, 744-750.
    15.“Merging Atom Disperse Silver and Carbon Nitride to a Joint Electronic System via Co-Polymerization with Silver Tricyanomethanide” Z. Chen, S. Pronkin, T. Fellinger, K. Kailasam, G. Vilé, D. Albani, J. Pérez-Ramírez, M. Antonietti and D. Dontsova. ACS Nano, 2016, 10, 3166–3175.
    16.Nickel as a co-catalyst for the photocatalytic hydrogen evolution on graphitic-carbon nitride (sg-CN): what is the nature of the active species? A. Indra, P. W. Menezes, K. Kailasam, D. Hollmann, M. Schröder, A. Thomas, A. Brückner and M. Driess. Chemical Communications, 2016,52, 104-107.
    17.“Complementing graphenes: One-dimensional interplanar charge transport in polymeric graphitic carbon nitrides” C. Merschjann, S. Tschierlei, T. Tyborski, K. Kailasam, S. Orthmann, D. Hollmann, T. Schedel-Niedrig, A. Thomas and S. Lochbrunner. Advanced Materials, 2015, 27, 7993-7999.
    18.“Synthesis of efficient photocatalysts for water oxidation and dye degradation reactions using CoCl2 eutectics” C. Fettkenhauer, X. Wang, K. Kailasam, M. Antonietti and D. Dontsova. Journal of Materials Chemistry A, 2015, 3, 21227-21232.
    19.“Hydrogen Evolution Reaction in a Large-Scale Reactor using a Carbon Nitride Photocatalyst under Natural Sunlight Irradiation” M. Schröder, K. Kailasam, J. Borgmeyer, M. Neumann, A. Thomas, R. Schomäcker and M. Schwarze. Energy Technology, 2015, DOI: 10.1002/ente.201500142.
    20.“Facile Synthesis of New, Highly Efficient SnO2/Carbon Nitride Composite Photocatalysts for Hydrogen Evolution Reaction” C. Fettkenhauer, G. Clavel, K. Kailasam, M. Antonietti and D. Dontsova. Green Chemistry, 2015, 17, 3350-3361.
    21.“Controlling Hydrogenation Selectivity with Pd Catalysts on Carbon Nitrides Functionalized Silica” T. Yuan, H. Gong, K. Kailasam, Y. Zhao, A. Thomas and J. Zhu. Journal of Catalysis, 2015, 326, 38-42.
    22.“Mesoporous Polymeric Carbon Nitride-Tungsten Oxide Composites for Enhanced Photocatalytic Hydrogen Evolution” K. Kailasam*, A. Fischer*, G. Zhang, J. Zhang, M. Schwarze, M. Schröder, X. Wang, R. Schomäcker and A. Thomas. ChemSusChem, 2015, 8, 1404-1410.
    23.“Using Nickel Manganese Oxide Catalysts for Efficient Water Oxidation” P. W. Menezes, A. Indra, O. Levy, K. Kailasam, V. Gutkin, J. Pfrommer and M. Driess. Chemical Communications, 2015, 51, 5005-5008.
    24.“Enhanced catalytic performance of MnxOy-Na2WO4/SiO2 for the oxidative coupling of methane using an ordered mesoporous silica support material” M. Yildiz, Y. Aksu, U. Simon, K. Kailasam, O. Goerke, F. Rosowski, R. Schomäcker, A. Thomas and S. Arndt. Chemical Communications, 2014, 50, 14440-14442.
    25."Applying thermo-destabilization of microemulsions as a new method for co-catalyst loading on mesoporous polymeric carbon nitride – towards large scale applications” M. Schröder, K. Kailasam, S. Rudi, K. Fündling, J. Riess, M. Lublow, A. Thomas, R. Schomäcker and M. Schwarze. RSC Advances, 2014, 4, 50017-50026.
    26.“Impact of the reaction conditions on the photocatalytic reduction of water on mesoporous polymeric carbon nitride under sunlight irradiation” M. Schröder, K. Kailasam, A. Thomas, R. Schomäcker and M. Schwarze. International Journal of Hydrogen Energy,2014, 39, 10108-10120.
    28.“Structure Activity Relationships in Graphitic and Sol-Gel-Derived Carbon Nitrides during Photocatalytic Hydrogen Production” D. Hollmann, M. Karnahl, S. Tschierlei, K. Kailasam, M. Schneider, J. Radnik, K. Grabow, U. Bentrup, H. Junge, M. Beller, S. Lochbrunner, A. Thomas and A. Brückner. Chemistry of Materials, 2014,26, 1727-1733.
    29.“Support Material Variation for the MnxOy-Na2WO4/SiO2 Catalyst” M. Yildiz, U. Simon, T. Otremba, Y. Aksu, K. Kailasam, A. Thomas, R. Schomäcker and S. Arndt. Catalysis Today, 2014,228, 5-14.
    30.“Adsorption removal of organic dyes on covalent triazine framework (CTF)” T. Wang, K. Kailasam, P. Xiao, G. Chen, L. Chen, L. Wang, J. Li and J. Zhu. Microporous and Mesoporous Materials, 2014, 187, 63-70.
    31.“Room Temperature Synthesis of Heptazine-Based Microporous Polymer Networks as Photocatalysts for Hydrogen Evolution” K. Kailasam*, J. Schmidt, H. Bildirir, G. Zhang, S. Blechert, X. Wang and A. Thomas*. Macromolecular Rapid Communications, 2013, 34, 1008-1013.
    32.“Development of a Reactor for Standardized Quantification of the Photocatalytic Hydrogen Production” M. Schwarze, M. Schröder, D. Stellmach, K. Kailasam, A. Thomas and R. Schomäcker. Chemie Ingeniuer Technik, 2013, 85, 500-507.
    33.“Quantification of Photocatalytic Hydrogen Evolution” M. Schwarze, D. Stellmach, M. Schröder, K. Kailasam, R. Reske, A. Thomas and R. Schomäcker. Physical Chemistry Chemical Physics, 2013, 15, 3466-3472.
    34.“Covalent triazine frameworks as heterogeneous catalyst for the synthesis of cyclic and linear carbonates from CO2 and epoxides” J. Roeser, K. Kailasam and A. Thomas. ChemSusChem, 2012, 5, 1793-1799.
    35.“Influence of periodic nitrogen functionality on the selective oxidation of alcohols” C. E. Chan-Thaw, A. Villa, G. M. Veith, K. Kailasam, L. A. Adamczyk, R. R. Unocic, L. Prati and A. Thomas. Chemistry – An Asian Journal, 2012, 7, 387–393.
    36.“Mesoporous carbon nitride–silica composites by a combined sol–gel/thermal condensation approach and their application as photocatalysts” K. Kailasam, J. D. Epping, A. Thomas, S. Losse and H. Junge. Energy & Environmental Science, 2011, 4, 4668–4674.
    37.“High-Surface-Area SBA-15 with Enhanced Mesopore Connectivity by the Addition of Poly(vinyl alcohol)” J. Zhu, K. Kailasam, X. Xie, R. Schomaecker and A. Thomas. Chemistry of Materials, 2011, 23, 2062–2067.
    38.“Supported Cobalt Oxide Nanoparticles As Catalyst for Aerobic Oxidation of Alcohols in Liquid Phase” J. Zhu, K. Kailasam, A. Fischer and A. Thomas. ACS Catalysis, 2011, 1, 342–347.
    39.“Mesoporous Melamine Resins by Soft Templating of Block-co-Polymer Mesophases” K. Kailasam, Y. –S. Jun, P. Katekomol, J. D. Epping, W. H. Hong and A. Thomas. Chemistry of Materials, 2010, 22, 428–434.
    40.“Alkyl chain grafting on Silica-Zirconia Mixed Oxides: Preparation and characterization” K. Kailasam, S. Mascotto, S. Gross, C. Maccatto and K. Müller. Journal of Materials Chemistry, 2010, 20, 2345–2355.
    41.“Fourier transform infrared spectroscopy and solid-state nuclear magnetic resonance studies of octadecyl modified metal oxides obtained from different silane precursors” K. Kailasam, M. M. Natile, A. Glisenti and K. Müller. Journal of Chromatography A, 2009, 1216, 2345-2354.
    42.“Octadecyl grafted MCM-41 silica spheres using trifunctionalsilane precursors – preparation and characterization” K. Kailasam, A. Fels and K. Müller. Microporous and Mesoporous Materials, 2009, 117, 136-147.
    43.“Physico-chemical characterization of MCM-41 silica spheres made by the pseudomorphic route and grafted with octadecyl chains” K. Kailasam and K. Müller. Journal of Chromatography A, 2008, 1191, 125-135 (Invited article for special edition on Column Packings 2007).
    44.“Solvent effects on the conformational order of triacontyl modified silica gels as evaluated by Fourier transform infrared spectroscopy” K. Kailasam, G. Srinivasan and K. Müller. Journal of Chromatography A, 2006, 1134, 81-87.

*Corresponding Author

Book Chapters:
  • ST Nishanthi, Battula Venugopala Rao and Kamalakannan Kailasam “Chapter-12: Metal‐Free Organic Semiconductors for Visible‐Light‐Active Photocatalytic Water Splitting, Pages 329-363, 2018” in Visible Light‐Active Photocatalysis: Nanostructured Catalyst Design, Mechanisms, and Applications, Wiley‐VCH Verlag GmbH & Co. KGaA.
  • Sanyasinaidu Boddu, ST Nishanthi, Kamalakannan Kailasam “Chapter-15: Visible‐Light Heterogeneous Catalysts for Photocatalytic CO2 Reduction, Pages 421-446, 2018” in Visible Light‐Active Photocatalysis: Nanostructured Catalyst Design, Mechanisms, and Applications, Editor: Srabanti Ghosh, Wiley‐VCH Verlag GmbH & Co. KGaA.
  • Devadutta Nepak, Vijay K. Tomer and Kamalakannan Kailasam. “Chapter-3: Carbon Nitrides (g-C3N4) and Covalent Triazine Frameworks (CTFs), Pages 67-102, 2018” in Metal-free Functionalized Carbons in Catalysis: Synthesis, Characterization and Applications, Editors: Alberto Villa and Nikolaos Dimitratos, Royal Society of Chemistry.
Articles in International Magazines:
    • Contribution in “Three ways nanomaterials could help combat climate change and prevent pollution” by Bhavya Khullar, in ENSIA on August 18, 2017.
    • Weblinks: https://ensia.com/articles/nanomaterials-environment/
      http://www.downtoearth.org.in/news/three-ways-nanomaterials-could-help-combat-climate-change-and-prevent-pollution-58510

     

CONTACT INFORMATION :

Tel: 0172 - 2210075
Email Id : kamal(at)inst(dot)ac(dot)in, kkamal17@gmail.com

Office Address :

Institute of Nano Science & Technology
Habitat Centre, Sector - 64, Phase X, Mohali